Creating a soft duotone portrait in Photoshop

Before

After
Here are steps to create the after version shown above:
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Duplicate the image (optional)
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Convert image mode to lab color
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Select the lightness channel
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Convert image to grayscale mode (discarding the other channels)
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Convert the image to duotone mode
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Select the color tone you want (or OK for the default as in this example)
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Convert image to RGB mode
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Duplicate the current layer
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Select that duplicate layer
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Filter > Blur - Gaussian Blur (20 pixels)
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Set current layer’s blend mode to multiply
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Flatten image
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Duplicate the current layer
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Select the duplicate layer
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Set the blend mode to screen
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Flatten the image
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Duplicate the current layer
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Desaturate the duplicate layer
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Invert the layer
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Filter > Blur > Gaussian blur (3 pixels)
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Set the layer’s blend mode to soft light
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Set the layers opacity to 50%
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Merge visible layers
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Dulicate current layer
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Set the blend mode to screen
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Filter > Sharpen > Unsharp Mask (Amount 20%, Radious 50 pixels, Threshold 0)
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Flatten Image
That is it. As you work through the steps, there will be times in the process where you might not think that your image will end up the way you want it; however, once all of the steps are completed, you will get results similar to the after image shown above.
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